Structure and Aromaticity of Monocyclic Conjugated Polyenes

نویسندگان

چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Genealogy of Conjugated Acyclic Polyenes.

Based on the total π-electron energies Eπs of Hückel Molecular Orbital (HMO) method for all the possible isomers of conjugated acyclic polyenes (C₂nH₂n+2) up to n = 7, the structure-stability relation of the possible isomers was analyzed. It was shown that the mean length of conjugation L can roughly predict the ordering of stability among isomers, while the Z-index, or Hosoya-index, can almost...

متن کامل

Aromaticity of polycyclic conjugated hydrocarbons.

G. Clar 6n Rule versus Hückel 4n + 2 Rule 3464 H. Hydrocarbons versus Heteroatomic Systems 3465 IV. Hidden Treasures of Kekulé Valence Structures 3466 A. Conjugated Circuits 3467 B. Innate Degree of Freedom 3470 C. Clar Structures 3472 V. Graph Theoretical Approach to Chemical Structure 3473 A. Metric 3473 B. Chemical Graphs 3473 C. Isospectral Graphs 3473 D. Embedded Graphs 3475 E. Partial Ord...

متن کامل

Chemistry-Relevant Isospectral Graphs. Acyclic Conjugated Polyenes*

Abstract: By using the topological index Z and Z-counting polynomial proposed by the present author isospectral (IS) pairs of acyclic conjugated polyenes (C2nH2n+2) were studied. Besides the hitherto known smallest pair of n = 6, four and twenty seven pairs of n = 7 and 8, respectively, were first reported. Inspection of these results revealed several new features of IS tree graphs, i.e., appea...

متن کامل

Synthesis and Optical Properties of Terminally Substituted Conjugated Polyenes

Compound 1 reacts with compounds of the transition metals Fe, Ni, Rh, Mn, Cr, or M o to form dark brown to black solids, whose insolubility and relative nonvolatility make their characterization difficult. However, black “FePlo,” formed immediately upon reaction with FeCI, in T H F at room temperature exhibits-like 1 -an IR band at 8 15 cm I, which is evidence for an intact aromatic Ps ring as ...

متن کامل

Aromaticity/Antiaromaticity in Cyclic Conjugated Hydrocarbons

The physical reason for aromaticity/antiaromaticity was determined. The conclusion was reached after interpreting Hobey's mathematical results that were given in the study of the energy difference between the one-dimensional linear and cyclic particles-in-a-box models. We first revealed that the Huckel theory and particles-in-a-box model are simply different ways of solving the same Schr6dinger...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Daxue huaxue

سال: 2021

ISSN: ['1000-8438']

DOI: https://doi.org/10.3866/pku.dxhx202108007